资源简介
编号:CTSO-2C701a
日期:2022 年 5 月 27 日局长授权
批准:
中国民用航空技术标准规定
本技术标准规定根据中国民用航空规章《民用航空材料、零部件和机载设备技术标准规定》(CCAR37)颁发。中国民用航空技术标准规定是对用于民用航空器上的某些航空材料、零部件和机载设备接受适航审查时,必须遵守的准则。
含合成烃的民用航空喷气燃料
1. 目的
本技术标准规定(CTSO)适用于为含合成烃的民用航空喷气燃料申请技术标准规定项目批准书(CTSOA)的制造人。本技术标准规定项目(CTSO)规定了含合成烃的民用航空喷气燃料为获得批准和使用适用的 CTSO 标记进行标识所必须满足的最低性能标准。
2. 适用范围
本CTSO 适用于自其生效之日起提交的CTSOA 申请。按本CTSO批准的含合成烃的民用航空喷气燃料,其设计大改应按 CCAR-21 要求重新申请 CTSOA。
含合成烃的民用航空喷气燃料是指含传统喷气燃料和合成烃组分(Synthesized Hydrocarbons)的喷气燃料或共炼工艺生产的喷气燃料(Co-processing Aviation Turbine Fuels)。
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CAAC CTSO-2C701a
3. 要求
a .工艺要求
本 CTSO 标记的含合成烃的民用航空喷气燃料应满足通行产品标准的工艺要求。通行的产品标准有 GB 6537、ASTM D1655 和 ASTM D7566 等。
b .性能要求
含合成烃的民用航空喷气燃料以及其合成烃组分应满足通行产品标准的性能要求,以及按本 CTSO 所做的补充要求。通行产品标准有 GB 6537、ASTM D1655 和 ASTM D7566 等。GB 6537 中的添加剂T1502 和 T1602 的组分或性能要求见 CTSO-2C707 中的相关要求。本CTSO 所做的补充要求具体如下:
(1)合成烃组分性能要求
(i)已列入标准的合成烃组分
应满足 GB 6537 附录 B、附录 C,或 ASTM D7566 Annex A 的性能要求,并按照 ASTM D4054 开展部分特性性能,如化学特性、物理特性、电性能、地面处理性能和安全性。
已列入标准的合成烃组分见表 1。
(ii)新工艺生产的合成烃组分
指除本 CTSO 3 b(1)1)外的工艺生产的合成烃煤油组分。
应满足 ASTM D4054 优化审批路线(Fast Track Qualification)中的性能要求(见表 2)和组成要求(见表 3)。
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表 1 已列入标准的合成烃组分及性能要求
序号
合成烃组分
性能要求
1
费托合成油改质工艺生产的煤油组分(FT-SPK)
Fisher-tropsch Hydroprocessed-synthesized Paraffinic Kerosine
GB 6537 附录 B 或ASTM D7566 A1
2
酯类和脂肪酸类加氢改质工艺生产的煤油组分(HEFA-SPK)
Synthesized Paraffinic Kerosine from Hydroprocessed Esters and Fatty
Acids
GB 6537 附录 C 或ASTM D7566 A2
3
合成异构烷烃煤油组分(SIP)
Synthesized Iso-paraffins
ASTM D7566 A3
4
调入合成芳烃的费托合成链烷烃煤油组分(SPK/A)
Synthesized Paraffinic Kerosine Plus Aromatics
ASTM D7566 A4
5
醇制喷气燃料工艺生产的煤油组分(ATJ-SPK)
Alcohol-to-jet Synthetic Paraffinic Kerosene
ASTM D7566 A5
6
合成催化热裂解工艺生产的煤油组分(CHJ)
Synthesized Catalytic Hydrothermolysis Jet
ASTM D7566 A6
7
源于藻类的烃/酯/脂肪酸加氢工艺生产的煤油组分(HC-HEFA SPK) Synthesized Paraffinic Kerosine from Hydroprocessed Hydrocarbons,
Esters and Fatty Acids
ASTM D7566 A7
表 2 新工艺的合成烃组分性能要求
项目
指标
试验方法
组成
总酸 值 ( 以 KOH
不大于计)/(mg/g)
0.015
GB/T 12574、ASTM D3242、IP 354
流动性
冰点不高于
-40
GB/T 2430、SH/T 0770、ASTM
D2386、ASTM D5972、ASTM
D7153、ASTM D7154、IP 16、IP
435、IP 528、IP 529
黏度(-40℃)/(mm2/s) 不大于
12.0
GB/T 30515、ASTM D445、ASTM D7042、ASTM D7945、IP 71
挥发性
闪点(闭口)/℃
38~66
GB/T 5208、GB/T 21789、GB/T 21929、ASTM D56、ASTM D3828、
IP 170、IP 523
密度(15℃)/(kg/m3)
730~880
GB/T 1884、GB/T 1885、SH/T
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0604、ASTM D1298、ASTM D4052、IP 160、IP 365
须同时符合馏程与模拟蒸馏要求
初馏点 IBP/℃
10% 回收 温度(T10)/℃
30% 回收 温度(T30)/℃
50% 回收 温度(T50)/℃
70% 回收 温度(T70)/℃
90% 回收 温度(T90)/℃
终馏点 FBP/℃
残留量(体积分数)/% 不大于
损失量(体积分数)/% 不大于
T10-IBP /℃ 不低于
T50-T10 /℃ 不低于
T90-T50 /℃ 不低于
FBP-T90 /℃ 不低于
馏程
模拟蒸馏
馏程:GB/T 6536、ASTM D86、IP
123
模拟蒸馏:SH/T 0558、ASTM
D2887、IP 406
130~190
100~140
150~200
130~160
160~210
160~185
170~225
180~210
175~240
200~230
180~265
225~260
195~296
250~330
1.5
-
10
20
15
35
25
燃烧性
十六烷值/min
35~60
NB/SH/T 0883、ASTM D6890
安定性
热安定性(2.5 h)
温度/℃ 不低于
压力降/mmHg 不大于
管壁评级/级
表面沉积物厚度/nm 不大于
325
小于 3, 且无孔雀蓝
色或异常沉淀物
85
GB/T 9169、ASTM D3241、IP 323
抗氧剂/(mg/L)
17~24
FAME/(mg/kg) 不大于
IP 585
表 3 新工艺的合成烃组分组成要求
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烃类组分
烷烃含量(质量分数)/%
C8、C9、C10、C11、C12、 C13、C14、C15、C16
报告
不大于
环烷烃含量 ( 质量 分
数)/%
30
芳烃含量(质量分数)/% 不大于
C8、C9、C10、
C11、C12、C13、C14、
C15、C16
萘系烃不大于
芳烃总含量的 5.0%
四氢萘和吲哚不大于
芳烃总含量的 30%
碳氢含量(质量分数)/% 不小于
99.5
SH/T 0656、ASTM D5291
非烃类组分
非烃组成/(mg/kg)
氮不大于
SH/T 0657、ASTM D4629、IP 379
水不大于
75
GB/T 11133、ASTM D6304、IP 438
硫不大于
GB/T 17040、SH/T 0689、ASTM D2622、ASTM D5453
金属元素/(mg/kg)
铝、钙、钴、铬、铜、铁、钾、锂、镁、锰、
钼、钠、镍、磷、铅、钯、铂、锡、锶、钛、钒、锌
每种金属 0.1
NB/SH/T 0892、ASTM D7111
铜/(µg/kg) 不大于
SH/T 0102、ASTM D6732
卤素含量/(mg/kg) 不大于
ASTM D7359
痕量 物质 - 有机 物含 量/(mg/kg)
酚类、苯胺类、吲哚类、喹啉类、四氢喹啉类、吡啶类、咔唑类、酮类、环酮类、醇酯类、醛类、醚类、邻苯二甲酸酯类、其他痕量有机物等
(2)含合成烃的民用航空喷气燃料性能要求
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(i)调合比例要求
FT-SPK、HEFA-SPK、ATJ-SPK、SPK/A 或 CHJ 合成烃组分可与符合 GB 6537 的 3 号喷气燃料调合使用,也可以与符合 ASTM D1655 的 Jet A-1 调合使用。调合产品中合成烃组分的体积分数不大于 50%。
SIP 或 HC-HEFA SPK 或通过本 CTSO 批准的新工艺生产的合成烃组分可与符合 GB 6537 的 3 号喷气燃料调合使用,也可以与符合ASTM D1655 的 Jet A-1 调合使用。调合产品中合成烃组分的体积分数不大于 10%。
(ii)调合产品性能要求
与 3 号喷气燃料调合使用的添加剂应符合 GB 6537 的要求,调合后产品除应满足 GB 6537-2018 表 1 的要求外,芳烃含量(体积分数)应不低于 8.0%,馏出温度 T50-T10 不低于 15℃, T90-T10 不低于 40℃。
与 Jet A-1 调合使用的添加剂应符合 ASTM D7566 的要求,调合后的产品应满足 ASTM D7566-21 Table 1 Jet A-1 的要求。
按本 CTSOb(2)(i)规定调合比例的含合成烃 FT-SPK、HEFA- SPK、SPK/A、SIP、ATJ-SPK、CHJ 或 HC-HEFA SPK 组分的民用航空喷气燃料,还应按照 ASTM D4054 开展部分特性性能和部分非金属材料相容性试验。特性性能如化学特性、物理特性、电性能、地面处理性能和安全性以及初始材料相容性。非金属材料相容性使用的材料类型包括胶粘剂、涂层、密封材料(密封胶、O 型圈和密封圈)以
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及薄膜。
(iii)共炼工艺所使用的原料应满足 ASTM D1655-21aAnnex A1要求。共炼工艺生产的产品除满足 ASTM D1655-21a Table 1 的性能要求外,还应满足 ASTM D1655-21a Table A1.1 的要求。
c .其他要求
含合成烃的民用航空喷气燃料中合成烃组分体积分数超过本CTSO b(2)1)的规定,应按照 ASTM D4054 进行试验,并满足该标准要求。
d .检验机构
所有的试验均应在局方认可的检测机构或在局方的监督下进行。
e .偏离
如果采用替代或等效的符合性方法来满足本 CTSO 规定的最低性能标准要求,则申请人必须表明产品保持了等效的安全水平。申请人应按照 CCAR-21-R4 第 21.368 条(一)要求申请偏离。
4. 标记
a .含合成烃的民用航空喷气燃料产品质量合格证及其他相关文
件至少应标注以下内容,但不限于:
(1)合成烃组分生产工艺和标准;
(2)局方批准的 CTSOA 证件号对应的 CTSO 标准号;
(3)含合成烃的民用航空喷气燃料中合成烃组分体积分数;
(4)生产单位的名称和地址;
(5)生产日期、生产数量和批次号。
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b .合成烃的产品质量合格证及含合成烃的民用航空喷气燃料产
品质量合格证可参考附录 1 和附录 2 所示。
5. 资料要求
申请人应提交相关技术资料以支持设计和生产批准,包括:
a .CCAR-21 中有关申请 CTSOA 的资料;
b .相关标准或规范;
c .原料情况说明;
d .生产工艺技术资料;
e .产品的化学品安全技术说明书;
f.局方要求的其他材料。
6. 应用说明
申请人取得 CTSOA 后,还应获得装机批准。若符合的产品标准已列入了相应航空器和发动机的型号合格数据单(TCDS)、补充型号合格证(STC)或其他型号设计批准文件,可直接使用,不再进行装机批准。
7. 引用文件
a.GB 标准可以从下列地址购买:中国标准出版社,北京复兴门外三里河北街 16 号,010-68523946。
b.SH 标准可从以下地址订购:中国石化出版社有限公司,北京市东城区安定门外大街 58 号,010-84271850。
c.ASTM 标准可以从下列地址购买:ASTM, 100 Barr Harbor Drive,
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West Conshohocken PA 19428-2959。
d .IP 标准可以从下列地址购买:Energy Institute, 61 New Cavendish Street, London, United Kingdom, W1G 7AR。
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附录 1
费托工艺合成烃组分(FT-SPK)产品质量合格证(示例)
合成烃组分名称:费托合成油改质工艺生产的煤
产品标准:GB 6537-2018油组分(FT-SPK)
CTSOA 证件号: CTSO 标记:CTSO-2C701
生产单位: 生产地址:
产品数量及批号: 生产日期:
指标要求
测试结果
总酸值(以 KOH 计)/(mg/g)
GB/T 12574
馏程须同时符合以下两个要求
GB/T 6536
10%回收温度(T10)/℃
不高于
205
50%回收温度(T50)/℃
90%回收温度(T90)/℃
终馏点/℃
300
T90-T10 /℃
不低于
22
残留量(体积分数)/%
损失量(体积分数)/%
SH/T 0558
闪点/℃
38
GB/T 21789
密度(20℃)/(kg/m3)
730~770
GB/T 1884
GB/T 1885
冰点/℃
GB/T 2430
热安定性(325℃, 2.5 h)压力降/kPa
3.3
小于 3, 且无
孔雀蓝色或异
常沉淀物
GB/T 9169
烃类组成(质量分数)/%环烷烃
SH/T 0606
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芳烃
烷烃
碳和氢
0.5报告99.5
SH/T 0656
氮不大于
水不大于
硫不大于
金属含量/(mg/kg)
铝、钙、钴、铬、铜、铁、钾、锂、
镁、锰、钼、钠、镍、磷、铅、钯、铂、 不大于
锡、锶、钛、钒、锌
卤素含量/(mg/kg) 不大于
SH/T 0657
GB/T 11133
SH/T 0689
NB/SH/T 0892
添加剂
结论:
检验员:
审核员:
批准人:
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附录 2
含合成烃的民用航空喷气燃料产品质量合格证(示例)
产品牌号:含合成烃的 3 号喷气燃料产品标准:GB 6537-2018
合成烃生产工艺及调合比例:
外观
室温下清澈透
明,目视无不
溶解水及固体
物质
目测
颜色
GB/T 3555
总酸值(以 KOH 计)/(mg/g) 不大于
芳烃含量(体积分数)/%
烯烃含量(体积分数)/% 不大于
总硫(质量分数)/% 不大于
硫醇硫(质量分数)/% 不大于
或博士试验
直馏组分(体积分数)/%
加氢精制组分(体积分数)/%
加氢裂化组分(体积分数)/%
合成烃组分(体积分数)/%
共炼的合成烃比例(体积分数)/%
8.0~25.0
5.0
0.20
0.0020通过
GB/T 11132
GB/T 1792
NB/SH/T 0174
10%回收温度(T10)/℃ 不高于
20%回收温度(T20)/℃
50%回收温度(T50)/℃ 不高于
终馏点 FBP/℃ 不高于
残留量(体积分数)/% 不大于
损失量(体积分数)/% 不大于
T50-T10 /℃ 不低于
T90-T10 /℃ 不低于
报告205报告
232报告
40
闪点(闭口)/℃ 不低于
775~830
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冰点/℃ 不高于
运动黏度(-20℃)/(mm2/s) 不大于
-47
8.0
GB/T 265
净热值/(MJ/kg) 不小于
烟点/mm 不小于
或烟点最小为 20 mm 时,
萘系烃含量(体积分数)/% 不大于
42.8
25.0
3.0
GB/T 384
GB/T 382
SH/T 0181
腐蚀性
铜片腐蚀(100℃, 2 h) /级不大于
GB/T 5096
热安定性(260℃, 2.5 h)
压力降/kPa 不大于
洁净性
胶质含量/(mg/100mL) 不大于
固体颗粒污染物含量 /(mg/L) 不大于
1.0
GB/T 8019
SH/T 0093
导电性
电导率/(pS/m)
50~600
GB/T 6539
水分离指数
未加抗静电剂不小于
加入抗静电剂不小于
70
SH/T 0616
润滑性
磨痕直径 WSD/mm 不大于
0.85
SH/T 0687
抗静电剂
初次加入量 /(mg/L) 不大于
抗磨剂/(mg/L) 不大于
20.0
17.0~24.0
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Number: CTSO-2C701a
Date of approval: May 27, 2022
Approval by: Yang Zhenmei
China Civil Aviation Technical Standard Order
This technical standard order is issued in accordance with Technical Standard Order for Civil Aviation Materials, Parts and Airborne Equipment (CCAR37), a China Civil Aviation Regulation. China Civil Aviation Technical Standard Order is the mandatory regulation for the airworthiness certification of certain civil aircraft materials, parts and airborne equipment.
Civil Aviation Jet Fuel Containing Synthesized Hydrocarbons
1. Purpose
This China Civil Aviation Technical Standard Order (CTSO) is for manufacturers applying for civil aviation jet fuel containing synthesized hydrocarbons CTSO authorization (CTSOA). This CTSO prescribes the minimum performance standards that civil aviation jet fuel containing synthesized hydrocarbons must first meet for approval and identification with the applicable CTSO marking.
2. Applicability
This CTSO is applicable for new applications since CTSO goes into effect. Major design changes to civil aviation jet fuel containing synthesized hydrocarbons approved under this CTSO shall require a new authorization in accordance with CCAR-21.
Civil aviation jet fuel containing synthesized hydrocarbons is the jet fuel comprising conventional jet fuel blending with synthetic blending component or producing by co-processing.
3. Requirements
a. Process requirements
Civil aviation jet fuel containing synthesized hydrocarbons marked by this CTSO marking shall meet the process requirements of current product specifications which include GB 6537, ASTM D1655 and ASTM D7566, etc.
b. Performance requirements
Civil aviation jet fuel containing synthesized hydrocarbons and its synthetic blending component shall meet the performance requirements of GB 6537, ASTM D1655 and ASTM D7566, and the additional requirements specified in this CTSO. Components or performance requirements of additives in GB 6537 shall be according to CTSO-2C707. Additional requirements in this CTSO is as follows.
(1) Performance requirements for synthetic blending components
(i) Historically accepted synthetic blending components
These synthetic blending components shall meet the performance requirements of GB 6537 Annex B, Annex C orASTM D7566 Annex A, and test some of fit for purpose properties in accordance with ASTM D4054. Fit for purpose properties include chemistry, bulk physical and performance properties, electrical properties, ground handling properties and safety.
Details of historically accepted synthetic blending components see
table 1.
(ii) Non-accepted synthetic blending components
Non-accepted synthetic blending component is produced by new process which not list in Section 3 b (1) 1) of this CTSO.
It shall meet the performance requirements (see table 2) and components requirements (see table 3) in the fast track qualification and approval process for new aviation turbine fuels ofASTM D4054.
Table 1 Performance Requirements for Historically Accepted Synthetic
Blending Components
S/N
Synthetic Blending Components
Performance
Requirements
Fisher-tropsch Hydroprocessed-synthesized Paraffinic Kerosine (FT-SPK)
GB 6537 Annex B orASTM D7566 A1
Synthesized Paraffinic Kerosine from Hydroprocessed Esters and Fatty Acids
(HEFA-SPK)
GB 6537 Annex C orASTM D7566 A2
Synthesized Iso-paraffin (SIP)
Synthesized Paraffinic Kerosine Plus Aromatics (SPK/A)
Alcohol-to-jet Synthetic Paraffinic Kerosene (ATJ-SPK)
Synthesized Catalytic Hydrothermolysis Jet (CHJ)
Algae-based Hydrocarbon-Hydroprocessed Esters and Fatty Acids Synthetic
Paraffinic Kerosene (HC-HEFA SPK)
Table 2 Performance Requirements for Synthetic Blending Component
Produced by New Process
Property
Target Value
Test Method
COMPOSITION
Acidity, total mg KOH/g Max
GB/T 12574, ASTM D3242 and IP 354
FLUIDITY
Freezing point, ℃ Max
GB/T 2430, SH/T 0770, ASTM D2386, ASTM D5972, ASTM D7153, ASTM D7154, IP 16, IP 435, IP 528 and IP 529
viscosity -40℃, mm2/s Max
GB/T 30515, ASTM D445, ASTM D7042, ASTM D7945 and IP 71
VOLATILITY
Flash point, ℃
GB/T 5208, GB/T 21789, GB/T 21929,
ASTM D56, ASTM D3828, IP 170 and
IP 523
Density at 15℃, kg/m3
730~880
GB/T 1884, GB/T 1885, SH/T 0604,
ASTM D1298, ASTM D4052, IP 160
and IP 365
Distillation-both of the following distillation
requirements shall be met: Initial boiling point,
temperature (IBP), ℃
10% recovered,
temperature (T10), ℃
30% recovered,
temperature (T30), ℃
50% recovered,
temperature (T50), ℃
70% recovered,
temperature (T70), ℃
90% recovered,
temperature (T90), ℃
Final boiling point, temperature (FBP), ℃
Distillation residue, percent
Distillation loss,
percent
T10-IBP, ℃
T50-T10, ℃
T90-T50, ℃
FBP-T90, ℃
Max
Min
Distillation
range
Simulated
distillation
Distillation range: GB/T 6536, ASTM
D86 and IP 123
Simulated distillation: S/T 0558, ASTM
D2887 and IP 406
COMBUSTION
Derived Cetane Number,
NB/SH/T 0883 and ASTM D6890
THERMAL STABILITY
Thermal stability (2.5 h at control temperature)
Temperature, ℃
Filter pressure drop, mmHg
Tube rating, class
nm avg over area of 2.5 mm2
Less
than
No peacock or
abnormal color deposits
GB/T 9169 and ASTM D3241 and IP
323
Antioxidant, mg/L
17~24
FAME, mg/kg Max
Table 3 Composition Requirements for Synthetic Blending Component
Hydrocarbon Composition
Paraffin-Distribution,
mass %
C8, C9, C10, C11, C12, C13, C14, C15 and C16
Report
Cycloparaffins, mass % Max
Aromatics, mass % Max
Aromatics-Distribution,
C8, C9, C10, C11, C12, C13, C14, C15 and C16
Naphthalenes, mass % Max
5.0 % of aromatic fraction
Tetralins and indans,
mass%
30 % of aromatic fraction
Carbon and hydrogen,
GB/T 0656 and ASTM D5291
Non-hydrocarbon
Composition, mg/kg
Nitrogen Max
SH/T 0657, ASTM D4629 and IP 379
Water Max
GB/T 11133, ASTM D6304 and IP 438
Sulphur Max
GB/T 17040, SH/T 0689, ASTM D2622
and ASTM D5453
Metals, mg/kg
Al, Ca, Co, Cr, Cu, Fe, K,
0.1 per metal
NB/SH/T 0892 and ASTM D7111
Li, Mg, Mn, Mo, Na, Ni, P, Pb, Pd, Pt, Sn, Sr, Ti, V and Zn
Cu, µg/kg Max
SH/T 0102 and ASTM D6732
Halogens, mg/kg Max
Trace Materials-organics, mg/kg
Phenols, Anilines,
Indoles, Quinolines,
Tetrahydroquinolines,
Pyridines, Carbazoles,
Ketones, Cycloketones, Alcohols&Esters,
Aldehydes, Ethers,
Phthalates and Other
(2) Performance requirements for civil aviation jet fuel containing synthesized hydrocarbons
(i)Blending ratio requirements
FT-SPK, HEFA-SPK, ATJ-SPK, SPK/A or CHJ can be blended with No. 3 Jet Fuel meeting GB 6537 or Jet A-1 meeting ASTM D1655, with up to 50 % by volume of the synthetic blending component.
SIP, HC-HEFA SPK, or non-accepted synthetic blending components marked by this CTSO can be blended with No. 3 Jet Fuel meeting GB 6537 or Jet A-1 meeting ASTM D1655, with up to 10 % by volume of the synthetic blending component.
(ii) Performance requirements of blended products
Synthetic blending components blended with No. 3 jet fuel shall use additives included in GB 6537. The blended product shall not only meet the requirements of GB 6537 table 1, but also have the aromatics volume content not less than 8.0%, the distillation slope T50-T10 not less than
15℃ and T90-T10 not less than 40℃ .
Synthetic blending components blended with Jet A-1 shall use additives included in ASTM D7566. The blended product shall meet the requirements ofASTM D7566-21 table 1 Jet A-1.
Civil aviation jet fuel containing FT-SPK、HEFA-SPK、SPK/A、 SIP、ATJ-SPK、CHJ 或 HC-HEFA SPK synthesized hydrocarbons blending ration according to this CTSO b (2) (i), shall also test some of fit for purpose properties and nonmetallic materials compatibility in accordance with ASTM D4054. Fit for purpose properties include chemistry, bulk physical and performance properties, electrical properties, ground handling properties and safety, preliminary materials compatibility. Nonmetallic materials include adhesive, coating, sealing materials (sealant, o-ring, gasket) and film.
(iii) Feedstock of co-processing shall meet the requirements of ASTM D1655-21a Annex A1. In addition to meeting the performance requirements of ASTM D1655-21a table 1, co-processed product shall also meet the requirements ofASTM D1655-21a table A1.1.
c. Other requirements
If volume fraction of the synthetic blending component is beyond the limits of this CTSO b (2) 1), civil aviation jet fuel containing synthesized hydrocarbons and synthetic blending component shall be evaluated according to ASTM D4054.
d. Testing laboratory
All tests shall be conducted in laboratories approved by CAAC or under the supervision ofCAAC.
e. Deviation
For using alternate or equivalent means of compliance to the criteria in this CTSO, the applicant must show that the product maintains an equivalent level of safety. The applicant must apply for a deviation under the provision of section 21.368 in CCAR-21.
4. Marking
a. The quality certificate and other applicable documents of civil aviation jet fuel containing synthesized hydrocarbons shall mark at least the following information:
(1) Process and standard of synthetic blending components;
(2) CTSO and CTSOA number;
(3) Volume fraction of synthetic blending components;
(4) Manufacturer designation and address;
(5) Manufacture date, quantity and batch number.
b. Annex 1 and Annex 2 are examples of the refinery certificate quality of synthetic blending component and civil aviation jet fuel containing synthesized hydrocarbons.
5. Documents Requirements
The applicant shall submit the responsible documents as follows.
a. Documents for CTSOA application according to CCAR-21;
b. Standards or specifications;
c. Description of feedstock;
d. Description of manufacturing process;
e. Safety data sheet for chemical products (SDS);
f. Other documents required by CAAC.
6. Application Note
After CTSOA authorization, the applicant shall obtain aircraft installation approval. If product standards have already listed in the type certificate data sheets (TCDS), supplemental type certificate (STC) or or other design approval documents, the civil aviation jet fuel containing synthesized hydrocarbons is not essential for installation approval.
7. Referenced Documents
a. GB standards are available from:
Standard Press of China, No. 16, North Sanlihe Street, Fuxingmenwai, Beijing. Tel: 010-84271850.
b. SH standards are available from:
China Petrochemical Press Co., Ltd., No. 58, Andingmenwai Street, Dongcheng District, Beijing. Tel: 010-84271850.
c. ASTM standards are available from:
ASTM, 100 Barr Harbor Drive, West Conshohocken PA 19428-2959.
d. IP standards are available from:
Energy Institute, 61 New Cavendish Street, London, United Kingdom, W1G 7AR.
Annex 1
Fischer-Tropsch Synthetic Paraffinic Kerosene (FT-SPK)
Refinery Certificate Quality (Example)
Name of Synthetic blending Component:
Fischer Tropsch-Synthesized Paraffinic Standard: GB 6537-2018 Kerosene (FT-SPK)
CTSOANumber: CTSO: CTOS-2C701
Manufacturer designation: Manufacturer address
Product quantity and batch number: Manufacture date:
Limits
Results
Composition
Acidity, total mg KOH/g Max
Volatility
Distillation-both of the following requirements shall be met:
10% recovered (T10), ℃ Max
50% recovered (T50), ℃
90% recovered (T90), ℃
Final boiling point, ℃ Max
T90-T10, ℃ Min
Residue, vol % Max
Loss, vol % Max
Simulated distillation
10% recovered (T10), ℃ Max
Flash point, ℃ Min
Density at 20℃, kg/m3
730~770
Fluidity
Freezing point, ℃ Max
Stability
Thermal stability (325℃, 2.5 h)
Filter pressure drop, kPa Max
Tube rating, class Less
abnormal color
deposits
Hydrocarbon Composition, mass %
Cycloparaffins Max
Aromatics Max
0.5
Paraffins
Carbon and hydrogen Min
Non-hydrocarbons, Composition
mg/kg
Nitrogen Max
Water Max
Sulfur Max
Al, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Pd, Pt, Sn, Sr, Ti, V, Zn
0.1 for each
metal
Halogens, mg/kg Max
Additives
Conclusion:
Tested by:
Reviewed by:
Approved by:
Annex 2
Certificate of Analysis (Example)
Product Grade: No. 3 Jet Fuel containing
Standard: GB 6537-2018 synthesized hydrocarbons
Production Process and Blending Ratio of
Synthesized Hydrocarbons
CTSOANumber: CTSO: CTSO-2C701
Manufacturer designation: Manufacturer address:
Appearance
Clear, bright and
visually free from
solid matter and
undissolved water at
ambient fuel
temperature
Visual
Color
Aromatics, volume percent
Olefins, volume percent Max
8.0~25.0
Sulfur, total mass percent Max
Sulfur mercaptan, mass percent Max
0.0020
or Doctor test
Pass
Fractionation components, volume percent
Hydrotreating components, volume percent
Hydrocracked components, volume percent
Synthetic blending components, volume percent
Co-processed synthetic blending components, volume percent
Distillation range
Initial boiling point (IBP), ℃
20% recovered (T20), ℃
Final boiling point (FBP), ℃ Residue, percent
Loss, percent
T50-T10, ℃
T90-T10, ℃
232
Flash point (closed cup), ℃
775~830
Freezing point, ℃
Viscosity at -20℃, mm2/s
Combustion
Neat heat of combustion, MJ/kg Smoke point, mm
or when smoke point is no more
than 20 mm,
Naphthalenes, volume percent
Corrosion
Copper strip, 2 h at 100℃,
No.1
Thermal stability (260℃, 2.5 h) Filter pressure drop, kPa
Tube rating
Contaminants
Existent gum, mg/100mL
Particulate contamination, mg/L
Conductivity
Electrical conductivity, pS/m
50~600
Microseparometer, Rating
Without electrical conductivity additive
With electrical conductivity additive
Lubricity
Wear scar diameter (WSD), mm
Static dissipater additive
First dose, mg/L
- 14 -
Anti-wear additive, mg/L Max
17.0~24.0
(The English version is for reference only. In case of any discrepancy or ambiguity of meaning between this English translation and the Chinese version, the latter shall prevail.)

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